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some xtra notes !!!!!!!!!!!!!!!!!!!!!11 I_icon_minitimeMon Jun 22, 2009 2:26 pm by Vignesh

» MORE ABOUT SWINE FLU ........ BE AWARE n BEWAREE
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» At least 100 dead from swine flu worldwide
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» ...............SWINE FLU....................
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» Downloadable Text books : Biology
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» A suggestion- Academic side
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» Taxonomy Presentation
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» The rise and diversification of the english language
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 some xtra notes !!!!!!!!!!!!!!!!!!!!!11

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Lathika
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Lathika


Number of posts : 58
Age : 33
Location : Ernakulam
Job/hobbies : Everything especially sleeping...eating...haa DANCING
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Registration date : 2009-02-16

some xtra notes !!!!!!!!!!!!!!!!!!!!!11 Empty
PostSubject: some xtra notes !!!!!!!!!!!!!!!!!!!!!11   some xtra notes !!!!!!!!!!!!!!!!!!!!!11 I_icon_minitimeTue Feb 17, 2009 11:42 am

Stereochemistry
some xtra notes !!!!!!!!!!!!!!!!!!!!!11 Ch3+NuIn an SN1, the nucleophile attacks the planar carbocation. Since there
is an equally probability of attack on either face there will be a loss
of stereochemistry
at the reactive center and both possible products
will be observed.

some xtra notes !!!!!!!!!!!!!!!!!!!!!11 C+Nu

Since a carbocation intermediate is formed, there is the possibility
of rearrangements (e.g. 1,2-hydride or 1,2-alkyl shifts) to generate
a more stable carbocation (see later). This is usually indicated
by a change in the position of the halide compared to that of the original
-OH group, or a change in the carbon skeleton of the product when compared
to the starting material.
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